Monica Wynne

I am looking for 2 Wynne’s (could be Wynn or variant)
Denis and John. Both were born in Ireland. Lived in Centralia, Columbia County, PA
I think Denis Wynne born in Ireland around 1826 and died around 1875 but not sure. He is not buried in St. Ignatius Cemetery since it was prior to it being founded.
John Wynne his son was born around 1863 in Ireland. No idea when he died but he also is not buried at St. Ignatius. Can you tell me where I would find death records prior to 1906 for Columbia County?
Thanking you in advance for your help.

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